Trelagliptin (SYR-472, Zafatek), Novel Once-Weekly Treatment for Type 2 Diabetes, Inhibits Dipeptidyl Peptidase-4 (DPP-4) via a Non-Covalent Mechanism

نویسندگان

  • Charles E Grimshaw
  • Andy Jennings
  • Ruhi Kamran
  • Hikaru Ueno
  • Nobuhiro Nishigaki
  • Takuo Kosaka
  • Akiyoshi Tani
  • Hiroki Sano
  • Yoshinobu Kinugawa
  • Emiko Koumura
  • Lihong Shi
  • Koji Takeuchi
چکیده

Trelagliptin (SYR-472), a novel dipeptidyl peptidase-4 inhibitor, shows sustained efficacy by once-weekly dosing in type 2 diabetes patients. In this study, we characterized in vitro properties of trelagliptin, which exhibited approximately 4- and 12-fold more potent inhibition against human dipeptidyl peptidase-4 than alogliptin and sitagliptin, respectively, and >10,000-fold selectivity over related proteases including dipeptidyl peptidase-8 and dipeptidyl peptidase-9. Kinetic analysis revealed reversible, competitive and slow-binding inhibition of dipeptidyl peptidase-4 by trelagliptin (t1/2 for dissociation ≈ 30 minutes). X-ray diffraction data indicated a non-covalent interaction between dipeptidyl peptidase and trelagliptin. Taken together, potent dipeptidyl peptidase inhibition may partially contribute to sustained efficacy of trelagliptin.

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عنوان ژورنال:

دوره 11  شماره 

صفحات  -

تاریخ انتشار 2016